2021 Publications

  1. Gated Proton Release during Radical Transfer at the Subunit Interface of Ribonucleotide Reductase (J. Am. Chem. Soc)
  2.  Photoredox Nickel-Catalyzed C-S Cross-Coupling: Mechanism, Kinetics, and Generalization (J. Am. Chem. Soc)
  3.  Crystal structure of the RuPhos ligand (Acta Cryst.)
  4. Continuous electrochemical water splitting from natural water sources via forward osmosis (PNAS)
  5. Long-Lived Triplet Excited State in a Heterogeneous Modified Carbon Nitride Photocatalyst (J. Am. Chem. Soc.)
  6. Photohalogen elimination chemistry in low-valent binuclear nickel complexes (Polyhedron)
  7. Capturing the Complete Reaction Profile of a C-H Bond Activation (J. Am. Chem. Soc.)
  8. Impactful Role of Cocatalysts on Molecular Electrocatalytic Hydrogen Production (ACS Catal.)
  9. Syntheses and solid-state structures of two cofacial (bis)dipyrrin dichromium complexes in different charge states (Acta Cryst.)

2020 Publications

  1. Tertiary Amine-Assisted Electroreduction of Carbon Dioxide to Formate Catalyzed by Iron Tetraphenylporphyrin (ACS Energy Lett)
  2. Double Hangman Iron Porphyrin and the Effect of Electrostatic Nonbonding Interactions on Carbon Dioxide Reduction (J. Phys. Chem. Lett)
  3. General Paradigm in Photoredox Nickel‐Catalyzed Cross‐Coupling Allows for Light‐Free Access to Reactivity (Angew. Chem. Int. Ed.)
  4. Multielectron C–H photoactivation with an Sb(v) oxo corrole (Chem. Commun.)
  5. Practical challenges in the development of photoelectrochemical solar fuels production (Sustainable Energy Fuels)
  6. Synthesis of Hangman Chlorins (J. Org. Chem.)
  7. Direct Observation of Different One- and Two-Photon Fluorescent States in a Pyrrolo (3,2‐b) pyrrole Fluorophore (J. Phys. Chem. Lett)
  8. Subunit Interaction Dynamics of Class Ia Ribonucleotide Reductases: In Search of a Robust Assay (Biochemistry)
  9. Bacterial Phosphate Granules Contain Cyclic Polyphosphates: Evidence from 31P Solid-State NMR (J. Am. Chem. Soc.)
  10. Driving force dependence of inner-sphere electron transfer for the reduction of CO2 on a gold electrode (J. Chem. Phys.)
  11. Photocatalytic Hydromethylation and Hydroalkylation of Olefins Enabled by Titanium Dioxide Mediated Decarboxylation (J. Am. Chem. Soc.)
  12. Ribonucleotide Reductases: Structure, Chemistry, and Metabolism Suggest New Therapeutic Targets (Annu. Rev. Biochem)
  13. Role of electrolyte composition on the acid stability of mixed-metal oxygen evolution catalysts (Chem. Commun)
  14. Solar-driven tandem photoredox nickel-catalysed cross-coupling using modified carbon nitride (Chem. Sci.)
  15. Template-stabilized oxidic nickel oxygen evolution catalysts (PNAS)
  16. Valorization of CO2 through lithoautotrophic production of sustainable chemicals in Cupriavidus necator (Elsevier)
  17. General Paradigm in Photoredox Nickel-Catalyzed Cross-Coupling Allows for Light-Free Access to Reactivity (Angew.Chem.Int. Ed.)
  18. Solar-driven tandem photoredox nickel-catalysed cross-coupling using modified carbon nitride (Chem. Sci)
  19. Hybrid Inorganic-Biological Systems: Faradaic and Quantum Efficiency, Necessary but Not Sufficient (Joule)
  20. Harnessing the hidden powers of plants could help fix the climate (WIRED)

2019 Publications

  1. Carbon Dioxide Reduction by Iron Hangman Porphyrins (Organometallics)
  2. Dual-Phase Molecular-like Charge Transport in Nanoporous Transition Metal Oxides (J. Phys. Chem. C)
  3. High-Frequency and -Field EPR (HFEPR) Investigation of a Pseudotetrahedral CrIV Siloxide Complex and Computational Studies of Related CrIVL4 Systems (Inorg. Chem)
  4. Oxidative Degradation of Multi-​Carbon Substrates by an Oxidic Cobalt Phosphate Catalyst (Organometallics)
  5. Proton–Electron Conductivity in Thin Films of a Cobalt–Oxygen Evolving Catalyst (ACS Appl. Energy Mater)
  6. Artificial Photosynthesis at Efficiencies Greatly Exceeding That of Natural Photosynthesis (Acc.Chem.Res.)
  7. Interplay of Homogeneous Reactions, Mass Transport, and Kinetics in Determining Selectivity of the Reduction of CO2 on Gold Electrodes (ACS Cent. Sci.)
  8. Ligand Noninnocence in Nickel Porphyrins: Nickel Isobacteriochlorin Formation under Hydrogen Evolution Conditions (Inorg.Chem)
  9. Selective Production of Oxygen from Seawater by Oxidic Metallate Catalysts (ACS Omega)
  10. Practical challenges in the development of photoelectrochemical solar fuels production (Sustainable Energy Fuels)
  11. Selenocysteine Substitution in a Class I Ribonucleotide Reductase (Biochemistry)
  12. On the Conversion Efficiency of CO2 Electroreduction on Gold (Joule)

2018 Publications

  1. Structurally characterized terminal manganese(IV) oxo tris(alkoxide) complex (Chem. Sci.)
  2. Electrochemical trapping of metastable Mn3+ ions for activation of MnO2 oxygen evolution catalysts (Proc. Natl. Acad. Sci.)
  3. Oxygen Activation at a Dicobalt Centre of a Dipyridylethane Naphthyridine Complex (Dalton Transactions )
  4. Basis of dATP inhibition of RNRs (Journal of Biological Chemistry)
  5. Carbon Dioxide Reduction by Iron Hangman Porphyrins (Organometallics )
  6. Oxidative Degradation of Multi-​Carbon Substrates by an Oxidic Cobalt Phosphate Catalyst (Organometallics )
  7. Structurally characterized terminal manganese(IV) oxo tris(alkoxide) complex (Chemical Science)
  8. Halogen Photoelimination from SbV Dihalide Corroles ( Inorganic Chemistry)
  9. Properties of site-​specifically incorporated 3-​aminotyrosine in proteins to study redox-​active tyrosines: Escherichia coli ribonucleotide reductase as a paradigm (Biochemistry)
  10. Solar-​powered CO2 reduction by a hybrid biological | inorganic system (Journal of Photochemistry and Photobiology, A: Chemistry)
  11. Structurally characterized terminal manganese(IV) oxo tris(alkoxide) complex (Chemical science)
  12. Oxygen Reduction Reaction Promoted by Manganese Porphyrins (ACS Catalysis)
  13. Proton-​Electron Conductivity in Thin Films of a Cobalt-​Oxygen Evolving Catalyst (ACS Applied Energy Materials)
  14. Direct Electrochemical P(V) to P(III) Reduction of Phosphine Oxide Facilitated by Triaryl Borates (J. Am. Chem. Soc)
  15. Lithography-Free Electrochemical Patterning of Conductive Substrates with Metal Oxides (small-www.small-journal.com)
  16. General Strategy for Improving the Quantum Efficiency of Photoredox Hydroamidation Catalysis (J. Am. Chem. Soc)
  17. Light-driven fine chemical production in yeast biohybrids (Science)
  18. Photochemical Rescue of a Conformationally Inactivated Ribonucleotide Reductase (J. Am. Chem. Soc)
  19. Proton–Electron Conductivity in Thin Films of a Cobalt–Oxygen Evolving Catalyst (Appl.Energy.Mater)

2017 Publications

  1. Glutamate 350 Plays an Essential Role in Conformational Gating of Long-Range Radical Transport in Escherichia coli Class Ia Ribonucleotide Reductase (Biochem.)
  2. Formal Reduction Potentials of Difluorotyrosine and Trifluorotyrosine Protein Residues: Defining the Thermodynamics of Multistep Radical Transfer (J. Am. Chem. Soc.)
  3. Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films (Proc. Natl. Acad. Sci.)
  4. Solar Fuels and Solar Chemicals Industry (Acc. Chem. Res.)
  5. Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin (Acc. Catal.)
  6. In situ characterization of cofacial Co(IV) centers in Co4O4 cubane: Modeling the high-valent active site in oxygen-evolving catalysts (Proc. Natl. Acad. Sci.)
  7. Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid (Chem. Sci.)
  8. (13)​C-​Labeling the carbon-​fixation pathway of a highly efficient artificial photosynthetic system (Faraday discussions)
  9. Ambient nitrogen reduction cycle using a hybrid inorganic-​biological system (Proc. Natl. Acad. Sci.)
  10. Biological-​inorganic hybrid systems as a generalized platform for chemical production (Current Opinion in Chemical Biology)
  11. Conformationally Dynamic Radical Transfer within Ribonucleotide Reductase (J. Am. Chem. Soc.)
  12. Electrochemical Deposition of Conformal and Functional Layers on High Aspect Ratio Silicon Micro/Nanowires (Nano Lett.)
  13. Gold Corroles as Near-IR Phosphors for Oxygen Sensing (Inorg. Chem.)
  14. Multielectron, multisubstrate molecular catalysis of electrochemical reactions: Formal kinetic analysis in the total catalysis regime (Proc. Natl. Acad. Sci.)
  15. On the incompatibility of lithium–O2 battery technology with CO2 (Chem. Sci.)
  16. Scalable Syntheses of 4-Substituted Pyridine–Diimines (J. Org. Chem.)
  17. Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex (Inorg. Chem.)
  18. Self-healing catalysis in water (Proc. Natl. Acad. Sci.)
  19. Slow Magnetic Relaxation in Intermediate Spin S = 3​/2 Mononuclear Fe(III) Complexes (J. Am. Chem. Soc.)
  20. Solar Fuels and Solar Chemicals Industry (Acc. Chem. Res.)

2016 Publications

  1. Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism (Proc. Natl. Acad. Sci.)
  2. Electronic Structure of Copper Corroles (Angew. Chem. Int. Ed.)
  3. Activation of Electron-Deficient Quinones through Hydrogen-Bond-Donor-Coupled Electron Transfer (Angew. Chem. Int. Ed.)
  4. Oxygen Reduction Catalysis at a Dicobalt Center: The Relationship of Faradaic Efficiency to Overpotential (J. Am. Chem. Soc.)
  5. Probing Edge Site Reactivity of Oxidic Cobalt Water Oxidation Catalysts (J. Am. Chem. Soc.)
  6. Mechanistic Study for Facile Electrochemical Patterning of Surfaces with Metal Oxides (ACS Nano)
  7. Photochemical Generation of a Tryptophan Radical within the Subunit Interface of Ribonucleotide Reductase (Biochemistry)
  8. Water splitting–biosynthetic system with CO2 reduction efficiencies exceeding photosynthesis (Science)
  9. Photochemical Generation of a Tryptophan Radical within the Subunit Interface of Ribonucleotide Reductase (Biochemistry)
  10. Multi-electron reactivity of a cofacial di-tin(II) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙− (Chem. Sci.)
  11. EPR Spectroscopic Characterization of a Jahn-Teller Distorted (C3v→Cs) Four-Coordinate Chromium(V) Oxo Species (Isr. J. Chem.)
  12. X-ray Spectroscopic Characterization of Co(IV) and Metal–Metal Interactions in Co4O4: Electronic Structure Contributions to the Formation of High-Valent States Relevant to the Oxygen Evolution Reaction (J. Am. Chem. Soc.)
  13. Room temperature stable COx-free H2 production from methanol with magnesium oxide nanophotocatalysts (Sci. Adv.)
  14. A >200 meV Uphill Thermodynamic Landscape for Radical Transport in Escherichia coli Ribonucleotide Reductase Determined Using Fluorotyrosine-Substituted Enzymes (J. Am. Chem. Soc.)
  15. Stereoelectronic Effects in Cl2 Elimination from Binuclear Pt(III) Complexes (Inorg. Chem.)
  16. 13C-Labeling the carbon-fixation pathway of a highly efficient artificial photosynthetic system (Faraday Disc.)
  17. Charge-​Transfer Dynamics at the α​/β Subunit Interface of a Photochemical Ribonucleotide Reductase (J. Am. Chem. Soc.)
  18. EPR Spectroscopic Characterization of a Jahn‐Teller Distorted (C3v→Cs) Four‐Coordinate Chromium(V) Oxo Species (Israel Journal of Chemistry)
  19. Mechanistic Study for Facile Electrochemical Patterning of Surfaces with Metal Oxides (ACS Nano.)
  20. Multi-electron reactivity of a cofacial di-tin(II) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙− (Chem Sci.)

2015 Publications

  1. Tandem redox mediator/Ni(II) trihalide complex photocycle for hydrogen evolution from HCl (Chem. Sci.)
  2. Ultrafast Photoinduced Electron Transfer from Peroxide Dianion (J. Phys. Chem. B)
  3. Efficient solar-to-fuels production from a hybrid microbial–water-splitting catalyst system (Proc. Natl. Acad. Sci.)
  4. Photophysical Properties of β-Substituted Free-Base Corroles (Inorg. Chem.)
  5. Facile, Rapid, and Large-Area Periodic Patterning of Semiconductor Substrates with Submicron Inorganic Structures (J. Am. Chem. Soc.)
  6. Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions (J. Porph. Phthalocyanines)
  7. High-throughput patterning of photonic structures with tunable periodicity (Proc. Natl. Acad. Sci.)
  8. Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes (Nat. Comm.)
  9. Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes (J. Am. Chem. Soc.)
  10. Direct Interfacial Y731 Oxidation in α2 by a Photoβ2 Subunit of E. coli Class Ia Ribonucleotide Reductase (Chem. Sci.)
  11. The Solar Opportunity (The Bridge)
  12. Comparison of self-assembled and micelle encapsulated QD chemosensor constructs for biological sensing (Farady Discuss.)
  13. Micelle-Encapsulated Quantum Dot-Porphyrin Assemblies as in Vivo Two-Photon Oxygen Sensors (J. Am. Chem. Soc.)
  14. Oxygen Reduction Mechanism of Monometallic Rhodium Hydride Complexes (Inorg. Chem.)
  15. Catalytic Oxygen Evolution by Cobalt Oxido Thin Films (Top. Curr. Chem.)
  16. Modulation of Phenol Oxidation in Cofacial Dyads (J. Am. Chem. Soc.)
  17. Topological Magnon Bands in a Kagome Lattice Ferromagnet (Phys. Rev. Lett.)
  18. Halogen Photoelimination from Monomeric Nickel(III) Complexes Enabled by the Secondary Coordination Sphere (Organometallics)
  19. Nature of Activated Manganese Oxide for Oxygen Evolution (J. Am. Chem. Soc.)
  20. Charge-Transfer Dynamics at the α/β Subunit Interface of a Photochemical Ribonucleotide Reductase (J. Am. Chem. Soc.)

2014 Publications

  1. Metabolic Tumor Profiling with pH, Oxygen, and Glucose Chemosensors on a Quantum Dot Scaffold (Inorg. Chem.)
  2. Spectroscopic Studies of Nanoparticulate Thin Films of a Cobalt-Based Oxygen Evolution Catalyst (J. Phys. Chem. C)
  3. Nucleation and Growth Mechanisms of an Electrodeposited Manganese Oxide Oxygen Evolution Catalyst (J. Phys. Chem. C)
  4. A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid (J. Am. Chem. Soc.)
  5. Templated assembly of photoswitches significantly increases the energy-storage capacity of solar thermal fuels (Nat. Chem.)
  6. Electron-Transfer Studies of a Peroxide Dianion (Inorg. Chem.)
  7. Post-Synthetic Modification of Hangman Porphyrins Synthesized on the Gram Scale (ChemSusChem)
  8. Electrocatalytic H$$_2$$ Evolution by Proton-Gated Hangman Iron Porphyrins (Organometallics)
  9. Halide-Bridged Binuclear HX-Splitting Catalysts (Inorg. Chem.)
  10. Ten-percent solar-to-fuel conversion with nonprecious materials (PNAS)
  11. Tandem redox mediator/Ni(II) trihalide complex photocycle for hydrogen evolution from HCl (Chem. Sci.)
  12. Photocrystallographic Observation of Halide-Bridged Intermediates in Halogen Photoeliminations (J. Am. Chem. Soc.) and writeup in Nature Chemistry
  13. Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins (PNAS)
  14. Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution (ACS Catal.)
  15. Kinetics of Hydrogen Atom Abstraction from Substrate by an Active Site Thiyl Radical in Ribonucleotide Reductase (J. Am. Chem. Soc.)
  16. Water Oxidation Catalysis by Co(II) Impurities in $$\ce{Co(III)_4O_4}$$ Cubanes (J. Am. Chem. Soc.)
  17. Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions (J. Porphyrins Phthalocyanines)

2013 Publications

  1. Acidolyis and oxygen atom transfer reactivity of a diiridium hydroperoxo complex (Dalton Trans.)
  2. Photoactivation of metal–halogen bonds in a Ni(II) NHC complex (Dalton Trans.)
  3. Conformational Control of Energy Transfer: A Mechanism for Biocompatible Nanocrystal-Based Sensors (Angew. Chem. Int. Ed.)
  4. Energy and environment policy case for a global project on artificial photosynthesis (Energy Environ. Sci.)
  5. Generation of a stable, aminotyrosyl radical-induced α2β2 complex of Escherichia coli class Ia ribonucleotide reductase (PNAS)
  6. Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst (J. Am. Chem. Soc.)
  7. Iron in a Trigonal Tris(alkoxide) Ligand Environment (Inorg. Chem.)
  8. Interfaces between water splitting catalysts and buried silicon junctions (Energy Environ. Sci.)
  9. Chromium(IV) Siloxide (Inorg. Chem.)
  10. Modeling integrated photovoltaic–electrochemical devices using steady-state equivalent circuits (Proc. Natl. Acad. Sci. U.S.A.)
  11. Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst (ChemSusChem)
  12. High-Field Magnetism of the S=5/2 Kagome-Lattice Antiferromagnet $$\ce{KFe_{3}(OH)_{6}(SO_{4})_{2}}$$ for the Magnetic Field in the Kagome-Plane (J. Low Temp. Phys.)
  13. Artificial photosynthesis as a frontier technology for energy sustainability (Energy Environ. Sci.)
  14. Stabilized CdSe-CoPi Composite Photoanode for Light-Assisted Water Oxidation by Transformation of a CdSe/Cobalt Metal Thin Film (ACS Appl. Mater. Interfaces)
  15. Intermediate-Range Structure of Self-Assembled Cobalt-Based Oxygen-Evolving Catalyst (J. Am. Chem. Soc.)
  16. Halogen Photoelimination from Dirhodium Phosphazane Complexes via Chloride-Bridged Intermediates (Chem. Sci.)
  17. Proton-Electron Transport and Transfer in Electrocatalytic Films. Application to a Cobalt-Based $$\ce{O_{2}}$$-Evolution Catalyst (J. Am. Chem. Soc.)
  18. Reversible, Long-Range Radical Transfer in E. coli Class Ia Ribonucleotide Reductase (Acc. Chem. Res.)
  19. Pacman and Hangman Metal Tetraazamacrocycles (ChemSusChem)
  20. An Artificial Water-Oxidizing Co Electro-Catalyst: Structure and Mechanism by in Situ X-Ray Absorption Spectroscopy in Photosynthesis Research for Food, Fuel and the Future, 15th International Conference on Photosynthesis.
  21. Modulation of Y356 Photooxidation in E. coli Class Ia Ribonucleotide Reductase by Y731 Across the α2:β2 Interface (J. Am. Chem. Soc.)
  22. Two-Photon Oxygen Sensing with Quantum Dot-Porphyrin Conjugates (Inorg. Chem.)
  23. Mechanism of Cobalt Self-Exchange Electron Transfer (J. Am. Chem. Soc.)
  24. Two-Electron HCl to H2 Photocycle Promoted by Ni(II) Polypyridyl Halide Complexes (J. Am. Chem. Soc.)
  25. Facet-Selective Growth on Nanowires Yields Multi-Component Nanostructures and Photonic Devices (J. Am. Chem. Soc.)

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